Sodium hexafluorophosphate CAS#21324-39-0

CAS Number: 21324-39-0

Chemical Formula: NaPF₆

Synonyms:

Sodium Hexafluorophosphate, Sodium Hexafluorophosphate(V), Anhydrous Sodium Hexafluorophosphate, 98% Sodium Hexafluorophosphate

Appearance: White crystalline powder, free-flowing solid powder, no visible foreign impurities.

MOQ (Minimum Order Quantity): 1 FCL (Full Container Load). The minimum order quantity is one full container load, quantity can be adjusted according to container type.

Product Overview

Sodium hexafluorophosphate (NaPF₆) is an inorganic fluorophosphate salt, appearing as free-flowing white crystalline powder. It features good solubility in polar organic solvents and stable electrochemical properties, widely adopted in analytical chemistry, organic synthesis and new energy research.

Sodium hexafluorophosphate is used as an ion pairing agent for the determination of cobalt(II) in water samples. It is used as an important raw material in the preparation of 2-chloro-1,3-bis(dimethylamino)trimethinium hexafluorophosphate.

Sodium hexafluorophosphate CAS#21324-39-0

Key Technical Specifications

  • CAS Number: 21324-39-0

  • Chemical Formula: NaPF₆ / F₆NaP

  • Molecular Weight: 167.95 g/mol

  • Appearance: White crystalline powder

  • Purity: ≥98%

  • MDL Number: MFCD00011122

  • Density: 2.369 g/cm³ at 25℃

  • Characteristic: Hygroscopic, needs moisture-proof storage

  • Sodium hexafluorophosphate Chemical Properties
    Melting point >200 °C (lit.)
    density 2.369 g/mL at 25 °C (lit.)
    storage temp. Store at room temperature, keep dry and cool
    solubility H2O: soluble5%, clear, colorless
    form Crystals
    Specific Gravity3.375
    color White to light gray
    PH2.0-4.0
    Water Solubility SOLUBLE
    Sensitive Hygroscopic
    Stability:Stable. Incompatible with strong acids.
    Major Applicationbattery manufacturing
    InChIInChI=1S/F6P.Na/c1-7(2,3,4,5)6;/q-1;+1
    InChIKeyKMADQUOCJBLXRP-UHFFFAOYSA-N
    SMILES[P+5]([F-])([F-])([F-])([F-])([F-])[F-].[Na+]
    CAS DataBase Reference21324-39-0(CAS DataBase Reference)
  •  
    Safety Information
    Hazard Codes C,Xi
    Risk Statements 20/21/22-34
    Safety Statements 26-36/37/39-45
    RIDADR UN 3260 8/PG 2
    WGK Germany 3
    F 3-10
    Hazard Note Irritant
    HazardClass 6.1
    PackingGroup III
    HS Code 28269090
    Storage Class8A - Combustible corrosive hazardous materials
    Hazard ClassificationsAcute Tox. 4 Dermal
    Acute Tox. 4 Inhalation
    Acute Tox. 4 Oral
    Eye Dam. 1
    Skin Corr. 1B

Application Scenarios

  1. Analytical Chemistry

    It works as an ion-pairing reagent for trace metal detection in aqueous matrices. Besides cobalt(II) testing in water samples, it supports qualitative and quantitative analysis of multiple inorganic ions in environmental water, industrial wastewater and saline solution systems.

  2. Organic Synthesis & Catalysis

    It acts as a raw material to prepare specialized hexafluorophosphate ionic salts such as 2-chloro-1,3-bis(dimethylamino)trimethinium hexafluorophosphate. It also serves as counter-ion source and phase transfer catalyst for synthesis of benzimidazole and quinoxaline derivatives.

  3. Sodium-ion Battery & Electrochemical Research

    As a classic sodium conducting salt, it is widely applied in lab-scale sodium-ion battery electrolyte formulation. It provides sodium ions and forms stable interfacial film, improving ionic conductivity for coin cell and sodium metal battery research.

  4. Material Science Research

    Used for preparing polymer composite solid electrolytes and functional ceramic precursors. It helps adjust ionic conductivity of polymer electrolyte membranes for supercapacitor and energy storage material development.

Packaging & Transportation

  • Standard Package: 25kg sealed PE-lined woven bag or 100kg / 150kg iron drum. Inner liner prevents moisture penetration.

  • MOQ: 1 FCL (Full Container Load). We can adjust loading quantity based on 20GP / 40GP container.

  • Transport Notes: This chemical is corrosive and hygroscopic. Keep away from rain, humidity and strong alkaline materials during sea/land shipment. Avoid heavy extrusion.

  • Storage Recommendation: Keep warehouse dry, sealed storage, temperature controlled, away from moisture.

Documents & Compliance

We supply complete supporting files for overseas tender and customs clearance:

✅ COA Certificate of Analysis

✅ MSDS Material Safety Data Sheet

✅ TDS Technical Data Sheet

✅ Certificate of Origin

✅ Factory test report

All documents can be issued in English to meet international buyer audit requirements.

After-sales Service

  • Pre-shipment inspection: We will conduct lab retest before loading to guarantee purity and appearance match COA.

  • Technical support: Our chemist team offers formulation guidance, handling advice and safety operation instructions.

  • Shipment tracking: We provide bill of lading copy, container loading photos and real-time logistics updates after departure.

  • Quality feedback channel: If any quality issue arises after receiving cargo, please provide test records and photos, we will discuss remedy plan quickly.

Client Cases

We have supplied sodium hexafluorophosphate for analytical reagent distributors, battery research institutes and fine chemical manufacturers across Middle East, Southeast Asia and Europe.

Our customers mainly use this material for water environment analysis, lab electrolyte R&D and fine chemical intermediate synthesis. We are experienced in full-container export and tender document submission for B2B industrial buyers.

FAQ

Q1: Is the 98% grade suitable for battery lab research?

A: 98% grade fits most academic and pilot sodium-ion battery research. Higher purity grades (99% / 99.5%) are available upon request for high-precision electrochemical tests.

Q2: Can we accept partial container instead of full FCL?

A: Our standard MOQ is 1 full container. For small trial orders, we can evaluate feasibility separately subject to production schedule.

Q3: What is the shelf life of sodium hexafluorophosphate?

A: 24 months under proper sealed, dry storage. Once the package is opened, consume quickly to avoid moisture absorption.

Q4: Which payment terms can be accepted?

A: T/T is our regular term. We can negotiate payment terms for tender projects.

Q5: Can you mark customized labels for the package?

A: Yes, custom outer packaging labels with customer company information are available.

Why Choose Us

Our factory strictly controls impurity content for inorganic fluorophosphate chemicals. We have stable monthly output and rich export experience for hazardous chemical cargo. We can prepare all certification packages required for international tender quotation, and support third-party inspection before shipment.

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