Polyisobutylene CAS#9003-27-4

Remarkable Low-Temperature Flexibility

Thanks to its ultra-low glass transition temperature, polyisobutylene avoids brittleness and stiffness in cold surroundings. It sustains steady elasticity and flexible ductility continuously at low temperatures, free from cracking or performance failure in cold working and application conditions.

Outstanding Chemical Inertness & Durability

With a saturated stable molecular structure, polyisobutylene delivers robust resistance to oxidation, chemical erosion and ageing degradation. It maintains stable physical and chemical properties over extended service periods, fit for durable industrial components and long-life consumer goods.

Wide-Range Customizable Molecular Weight & Viscosity

This polymer supports flexible customization across full low-to-high molecular weight ranges. Under the standard test condition of 100°C, its kinematic viscosity is adjustable between 5 cSt and 4,700 cSt, allowing customers to pick the exact grade matching their processing and formulation requirements.

Polyisobutylene (CAS: 9003-27-4) Product Introduction

PIB is a non-toxic saturated linear polymer presenting as water-white viscous liquid or semi-solid. Thanks to its ultra-low glass transition temperature, it maintains excellent elasticity and flexibility in cold conditions, while its stable molecular structure grants outstanding resistance against chemical erosion and ageing.

Customizable molecular weight enables flexible viscosity control ranging from 5 to 4,700 cSt (100°C). Higher-viscosity grades feature stronger tack and cohesive force for bonding scenarios.

Physical Properties

  • Form: Liquid / semi-solid (varies by molecular weight)

  • Color: Water-white to faint pale yellow

  • Odor: Almost odorless with subtle intrinsic scent

  • Viscosity: 5–4700 cSt @ 100°C, grade-dependent

  • Density: ~0.92 g/mL (25°C)

  • Solubility: Dissolves in mineral oils, hydrocarbon solvents and carbon disulfide; partially soluble in high-molecular alcohols and esters; insoluble in water, short-chain alcohols, ketones and acetic acid.

Application Range

  • Lubrication systems: Two-stroke oil, gear lubricants, grease, hydraulic oil, metalworking fluid

  • Adhesives: Pressure-sensitive adhesives, hot melt adhesives

  • Sealants: Automotive, tire and architectural sealing products

  • Stretch packaging films: Reinforces tear resistance, food-contact acceptable

  • Electrical insulation: Hydrophobic, non-conductive protective insulation

  • Food & personal care: Food-safe grade for chewing gum base production

  • Melting point 

    54-56 °C

    Boiling point 

    300 °C

    Density 

    0.92 g/mL at 25 °C (lit.)

    Tg

    -61

    Tg

    -62

    Tg

    -64

    Tg

    -75

    Refractive index 

    n20/D 1.51

    Fp 

    >212

    Fp 

    >482

    Form 

    slab/chunk

    Stability

    Stability Combustible. Incompatible with strong oxidizing agents.

    InChI

    InChI=1S/C4H8/c1-4(2)3/h1H2,2-3H3

    InChIKey

    VQTUBCCKSQIDNK-UHFFFAOYSA-N

    SMILES

    C=C(C)C

    EPA Substance Registry System

    Polyisobutylene (9003-27-4)

  • Safety & Handling

    PIB is non-toxic, yet basic protective measures are required. Keep sealed in cool dry storage, separate from high heat and strong oxidants. Wear gloves and safety goggles during operation.

  • Shelf Life

  • 36 months under proper storage conditions.

  • Core Strengths

    • Superior tack and adjustable viscosity

    • Great resistance to heat, chemical corrosion and UV oxidation

    • Fully hydrophobic, low electrical conductivity

    • Stable in storage: no volatilization, curing or solidification

  • A multi-purpose polymer with reliable durability for various industrial environments.

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