Citric acidCAS#77-92-9

Anhydrous citric acid is a naturally occurring substance and an intermediate metabolite in the physiological processes of both plants and animals. It is also one of the most extensively utilized organic acids in the food, pharmaceutical, and chemical industries. This compound appears as colorless, transparent, or semi-transparent crystals, as well as granular or fine powder. 

Product Details

Anhydrous citric acid is a naturally occurring substance and an intermediate metabolite in the physiological processes of both plants and animals. It is also one of the most extensively utilized organic acids in the food, pharmaceutical, and chemical industries. This compound appears as colorless, transparent, or semi-transparent crystals, as well as granular or fine powder. 

It is odorless, with a pronounced sour taste that is pleasantly tart yet slightly astringent afterward. When exposed to warm air, it gradually loses moisture (weathers), and in humid conditions, it shows slight deliquescence.

Citric acidCAS#77-92-9

Parameter

Melting point 153-159 °C (lit.)
Boiling point 248.08°C (rough estimate)
density 1.67 g/cm3 at 20 °C
bulk density560kg/m3
vapor density 7.26 (vs air)
vapor pressure <0.1 hPa (20 °C)
refractive index 1.493~1.509
FEMA 2306 | CITRIC ACID
Fp 100 °C
storage temp. 2-8°C
solubility Citric acid also dissolves in absolute (anhydrous) ethanol (76 parts of citric acid per 100 parts of ethanol) at 15 °C.
form grit
pka3.14(at 20℃)
color White
PH3.24(1 mM solution);2.62(10 mM solution);2.08(100 mM solution);
OdorOdorless
biological sourcesynthetic
Odor Typeodorless
explosive limit8%, 65°F
soluble in Water (1174g/L at 10°C, 1809g/L at 30°C, 3825g/L at 80°C). 
Sensitive Hygroscopic
λmaxλ: 260 nm Amax: 0.20
λ: 280 nm Amax: 0.10
Merck 14,2326
JECFA Numbr218
BRN 782061
Stability:Stable. Incompatible with bases, strong oxidizing agents, reducing agents, metal nitrates.
InChIKeyKRKNYBCHXYNGOX-UHFFFAOYSA-N
LogP-1.64
CAS DataBase Reference77-92-9(CAS DataBase Reference)
NIST Chemisty Reference1,2,3-Propanetricarboxylic acid, 2-hydroxy-(77-92-9)
EPA Substance Registry SystemCitric acid (77-92-9)

Safety Information

Hazard Codes Xi,C,T
Risk Statements 41-36/37/38-36/38-37/38-34-36-35-61-60
Safety Statements 26-39-37/39-24/25-36/37/39-45-36-53
RIDADR UN 1789 8/PG 3
WGK Germany 1
RTECS GE7350000
9
TSCA Yes
HS Code 2918 14 00
Hazardous Substances Data77-92-9(Hazardous Substances Data)
ToxicityLD50 in mice, rats (mmol/kg): 5.0, 4.6 i.p. (Gruber, Halbeisen)

 

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